The change of picture in approximate two-component relativistic theories: Expectation values of r, r(-1) and r(2)

Authors
Citation
M. Barysz, The change of picture in approximate two-component relativistic theories: Expectation values of r, r(-1) and r(2), POL J CHEM, 74(9), 2000, pp. 1329-1339
Citations number
27
Categorie Soggetti
Chemistry
Journal title
POLISH JOURNAL OF CHEMISTRY
ISSN journal
01375083 → ACNP
Volume
74
Issue
9
Year of publication
2000
Pages
1329 - 1339
Database
ISI
SICI code
0137-5083(200009)74:9<1329:TCOPIA>2.0.ZU;2-Q
Abstract
The change of picture for operators which arises in approximate two-compone nt relativistic theories is analysed formally and exemplified by the evalua tion of relativistic corrections to the distance operator, its square, and its inverse. The change of picture contribution to the expectation value of the distance operator is interpreted as an error arising from the use of o perators in what is called the Schrodinger picture. This is at variance wit h earlier interpretations of this contribution.