Some aspects of gradient structure development in cemented carbides at micr
oscopic and submicroscopic levels are considered. The gradient structures a
re shown to develop mainly due to the nonequilibrium process of the liquid
phase mass transfer in cemented carbides. Particular emphasis is placed on
the theoretical and experimental description of the process of treatment wi
th metal melts which allows the gradient structures at microscopic and subm
icroscopic levels to be obtained.