The theoretical performances of HCFC123, HFC134a, CFC11, and CFC12 hav
e been assessed as coolants. For a specific amount of desired energy,
more compression work is required for HCFC123 and HFC134a than for CFC
11 and CFC12. The differences are not very significant at high evapora
tion temperatures and hence HCFC123 and HFC134a should not be excluded
as alternative coolants. There is an optimum evaporation temperature
for each condensation temperature which yields the highest exergetic e
fficiency.