New polymer-bound haloarene chromium dicarbonyl isocyanide complexes: a successful study validating their use in solid-phase chemistry

Authors
Maiorana, S Baldoli, C Licandro, E Casiraghi, L de Magistris, E Paio, A Provera, S Seneci, P
Citation
S. Maiorana et al., New polymer-bound haloarene chromium dicarbonyl isocyanide complexes: a successful study validating their use in solid-phase chemistry, TETRAHEDR L, 41(37), 2000, pp. 7271-7275
Citations number
26
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
37
Year of publication
2000
Pages
7271 - 7275
Database
ISI
SICI code
0040-4039(20000909)41:37<7271:NPHCDI>2.0.ZU;2-6
Abstract
New fluorobenzene chromium dicarbonylisocyanide complexes have been synthes ized and evaluated in terms of their 'in solution' reactivity towards some nucleophiles. For the first time the polymer-bound isocyanides have been fo und to be valuable ligands for anchoring haloareneCr(CO)(3) complexes by me ans of their substitution for a CO group. The supported fluorobenzene compl ex reacted with nitrogen-nucleophiles. (C) 2000 Elsevier Science Ltd. All r ights reserved.