Let (G, mu) be a discrete symmetric random walk on a compact Lie group G wi
th step distribution mu and let T-mu be the associated transition operator
on L-2 (G). The irreducibles V-rho of the left regular representation of G
on L-2(G) are finite dimensional invariant subspaces for T-mu and the spect
rum of T-mu is the union of the sub-spectra sigma(T-mu\V-rho) on the irredu
cibles, which consist of real eigenvalues {lambda(rho 1),...,lambda(rho) di
m V-rho}. Our main result is an asymptotic expansion for the spectral measu
res
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along rays of representations in a positive Weyl chamber t(+)*, i.e. for se
quences of representations k(rho), k is an element of N with k --> infinity
. As a corollary we obtain some estimates on the spectral radius of the ran
dom walk. We also analyse the fine structure of the spectrum for certain ra
ndom walks on U(n) (for which T-mu is essentially a direct sum of Harper op
erators).