Copper(II) oxalate and oxamate complexes

Authors
Novosad, J Messimeri, AC Papadimitriou, CD Veltsistas, PG Woollins, JD
Citation
J. Novosad et al., Copper(II) oxalate and oxamate complexes, TRANSIT MET, 25(6), 2000, pp. 664-669
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
25
Issue
6
Year of publication
2000
Pages
664 - 669
Database
ISI
SICI code
0340-4285(200012)25:6<664:COAOC>2.0.ZU;2-3
Abstract
Reaction of Cu-II salts with phenanthroline and oxalate (ox) or oxamate (ox m) gives [Cu(phen)(ox)(H2O)] . H2O or [Cu(phen)(oxm)(H2O)] . H2O complexes while direct treatment of Cu-II salts with oxalate or oxamate gives [NH4](2 )[Cu(ox)(2)] and [Cu(oxm)(2)(H2O)(2)] respectively. The X-ray structures of one example of each system, aquo-oxamato-phenanthroline-copper(II)-dihydra te and the polymeric ammonium-bis(aquo)-tetraoxalato-dicopper(II)-dihydrate , are reported.