Mixed crystals in the system CuMoO4/ZnMoO4

Authors
Reichelt, W Weber, T Sohnel, T Dabritz, C
Citation
W. Reichelt et al., Mixed crystals in the system CuMoO4/ZnMoO4, Z ANORG A C, 626(9), 2000, pp. 2020-2027
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
626
Issue
9
Year of publication
2000
Pages
2020 - 2027
Database
ISI
SICI code
0044-2313(200009)626:9<2020:MCITSC>2.0.ZU;2-U
Abstract
The existence of a complet solid solution serie Cu1-xZnxMoO4 (0 less than o r equal to x less than or equal to 1) is confirmed. Single crystals were ob tained by chemical transport with different transport agents. The compositi ons and structures were characterized by EDX analysis, photometic analysis, and X-ray investigations on polycrystallin powders and single crystals. Th e substitution behaviour of (Cu1-xZnx)O-6(-) and (Cu1-xZnx)O-5-polyhedra is different and the reason for deviations from the Vegards rule are near x = 0.25.