Since the electroluminescence in polymer comes from the transportation and
combination of carriers in the electric field,it is essential to study the
polarization property of the excitation in polymer. First we obtain the ana
lytic solutions of exciton and biexciton,then their polarizabilities are ca
lculated using the Green function method. An important result is that we an
alytically proved that the polarizability of the exciton is positive and th
at of the biexciton is negative. It follows that the polarization will be r
eversed when the exciton becomes biexciton.