We investigate the spectral distortion of the cosmic microwave background (
CMB) caused by relativistic plasma. Within the Thomson regime, an exact ana
lytic expression for the photon scattering kernel of a momentum power-law e
lectron distribution is given, which is valid from the non- to the ultra-re
lativistic regime. The decrement in the photon spectrum saturates for elect
ron momenta above 3 m(e) c to that of an optically thick absorber with the
optical depth of the relativistic electrons given by the Thomson limit. Thu
s, the ultra-relativistic Sunyaev-Zeldovich (SZ) decrement measures the ele
ctron number and not the energy content. On the other hand, the relativisti
c SZ increment at higher frequencies depends strongly on the spectral shape
of the electrons, allowing for investigation of relativistic electron popu
lations with future instruments.
We calculate the expected Comptonization due to the energy release of radio
galaxies, which we estimate to be approximate to 3 . 10(66) erg Gpc(-3). W
e investigate Comptonization from (a) the part of the released energy which
is thermalized and (b) the relativistic, remnant radio plasma, which may f
orm a second, relativistic phase in the intergalactic medium, nearly unobse
rvable for present day instruments (presence of so called 'radio ghosts').
We find a thermal Comptonization parameter due to (a) of y approximate to 1
0(-6) and (b) an optical depth of relativistic electrons in old radio plasm
a of tau(rel) less than or equal to 10(-7). If a substantial fraction of th
e volume of clusters of galaxies is filled with such old radio plasma the S
Z effect based determination of the Hubble constant is biased to lower valu
es, if this is not accounted for. Finally, it is shown that a supra-thermal
population of electrons in the Coma cluster would produce a signature in t
he Wien-tail of the CMB, which is marginally detectable with a multifrequen
cy measurement by the Planck satellite. Such an electron population is expe
cted to exist, since its bremsstrahlung would explain Coma's recently repor
ted high energy X-ray excess.