In this work, the optimal temperature control of a styrene solution polymer
ization reactor with two different control algorithms is considered. DMC an
d PID control methods are used to accomplish the optimal temperature contro
l of the polystyrene reactor, Reactor optimal temperature profiles at diffe
rent initiator initiation concentrations were obtained by applying maximum
principle to the mathematical model of the free radical batch polymerizatio
n reactor to produce polystyrene with desired conversion and molecular weig
ht in a minimum time. The results obtained from the experimental implementa
tion of DMC and PID controller for the control of optimal temperature path
of the polymerization reactor were compared.