Composition monitoring and control play an essential role during a batch di
stillation cycle, but on-line composition analyzers are expensive, difficul
t to maintain and give delayed responses. Considering the need and lack of
a stochastic estimator for batch distillation columns, a discrete extended
Kalman filter (EKF) for binary and multicomponent systems has been develope
d and tested. The aim of the EKF was to provide reliable and real-time colu
mn composition profiles from few temperature measurements and easily availa
ble information. Accurate composition estimates and fast convergence were o
btained, and the EKF has confirmed its ability to incorporate the effects o
f noise (from both measurement and modeling). The number of sensors and the
observation frequency have shown to be important variables in the design o
f the EKF, especially for systems with fast dynamics. (C) 2000 Elsevier Sci
ence Ltd. All rights reserved.