The more potent odorants in a sample of medium-roasted Arabica coffee and i
n the corresponding brew were quantified. Large amounts (> 75 %) of acetald
ehyde, 2,3-butanedione. 2,3-pentanedione, vanillin and some furanones were
extracted from the coffee brew, whereas the yields of the more unpolar comp
ounds: such as 3-isobutyl-2-methoxypyrazine, (E)-beta-damascenone and the u
nstable 2-furfurylthiol were low (< 25 %). On the basis of quantitative dat
a an aroma model was prepared for the brew. In triangle tests, models conta
ining the complete set of 24 odorants were compared with a model missing on
e or more odorants. These experiments indicated that the aroma of the brew
was mainly caused by some alkylpyrazines, furanones and phenols, and by 2-f
urfurylthiol, methional and 3-mercapto-3-methylbutyl formate. The higher im
pact of both methional and the formate on the aroma of the brew and the low
er aroma activity of 4-vinylguaiacol were in contrast to results obtained i
n a previous study for ground coffee of the same provenance and roast degre
e.