Radiation processes in plastic scintillators (PSs) are studied to establish
that, first, macroradicals ore the main quenchers of radiation-induced lum
inescence in the PSs, and, second, molecular oxygen initiates the decay of
macroradicals. Based on these principles, PSs of a new type, whose radiatio
n resistance is by an order of magnitude higher than that of standard polys
tyrene scintillators, were developed and synthesized. The special nanoporou
s morphology of the new PSs is a system of open pores and channels, which p
rovide efficient penetration of molecular oxygen into the polymer bulk to p
roduce the antirad effect.