Comparison of comprehensive two-dimensional gas chromatography and gas chromatography - mass spectrometry for the characterization of complex hydrocarbon mixtures

In this paper, we compare the current separation power of comprehensive two -dimensional gas chromatography (GCxGC) with the potential separation power of GC-mass spectrometry (GC-MS) systems. Using simulated data, we may envi sage a GC-MS contour plot, that can be compared with a GCxGC chromatogram. Real examples are used to demonstrate the current potential of the two tech niques in the field of hydrocarbon analysis. As a separation technique for complex hydrocarbon mixtures, GCxGC is currently about as powerful as GC-MS is potentially powerful. CC-MS has not reached its potential separation po wer in this area, because a universal, soft ionization method does not exis t. The greatest advantage of GCxGC is, however, its potential for quantitat ive analysis. Because flame-ionisation detection can be used, quantitative analysis by GCxGC is much more robust, reliable and reproducible. (C) 2000 Elsevier Science B.V. All rights reserved.