Experimental study on moving neutralization reaction boundary created withthe strong reactive electrolytes of HCl and NaOH in agarose gel

Citation
Cx. Cao et al., Experimental study on moving neutralization reaction boundary created withthe strong reactive electrolytes of HCl and NaOH in agarose gel, J CHROMAT A, 891(2), 2000, pp. 337-347
Citations number
39
Categorie Soggetti
Chemistry & Analysis","Spectroscopy /Instrumentation/Analytical Sciences
Journal title
Volume
891
Issue
2
Year of publication
2000
Pages
337 - 347
Database
ISI
SICI code
Abstract
In this paper, a moving neutralization reaction boundary (MNRB) is created with the strong reactive electrolytes of HCl and NaOH in agarose gel. The m otions of the MNRB are investigated and compared with the predictions with the theory of the moving chemical reaction boundary (MCRB). The results sho w that, under appreciate experimental conditions, the experiments on the MN RB are exactly in coincidence with the predictions with the MCRB theory. Th us, the results excellently demonstrate that the MCRB theory is valid for t he MNRB formed with the strong reactive electrolytes of HCl and NaOH. Addit ionally, it is, as discussed in this paper, imperative to develop a method to obtain ionic mobility at different temperatures and ionic strengths, in order to investigate the movements of the MCRB more efficiently. (C) 2000 E lsevier Science B.V. All rights reserved.