Preparation and characterization of new Suprofen complexes of Fe(III), Co(II) and Ni(II)

Authors
Williams, PAM Baran, EJ Mercader, RC
Citation
Pam. Williams et al., Preparation and characterization of new Suprofen complexes of Fe(III), Co(II) and Ni(II), J COORD CH, 50(1), 2000, pp. 29-37
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
00958972 → ACNP
Volume
50
Issue
1
Year of publication
2000
Pages
29 - 37
Database
ISI
SICI code
0095-8972(2000)50:1<29:PACONS>2.0.ZU;2-4
Abstract
The preparation and properties of new complexes containing the biometals Fe (III), Co(II) and Ni(II) coordinated to the anti-inflammatory drug Suprofen are reported. The elemental analyses, together with the magnetic and therm al behavior and electronic, IR and Raman spectra, indicated the following s toichiometries for the latter two complexes: [M(Sup)(2)(H2O)(4)]. For the F e(III) complex, the generation of a dinuclear species may be proposed on th e basis of Fe-57 Mossbauer measurements.