First syntheses and X-ray structures of a meso-alkyl-substituted corrole and its Ga(III) complex

Authors
Simkhovich, L Goldberg, I Gross, Z
Citation
L. Simkhovich et al., First syntheses and X-ray structures of a meso-alkyl-substituted corrole and its Ga(III) complex, J INORG BIO, 80(3-4), 2000, pp. 235-238
Citations number
19
Categorie Soggetti
Biochemistry & Biophysics","Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF INORGANIC BIOCHEMISTRY
ISSN journal
01620134 → ACNP
Volume
80
Issue
3-4
Year of publication
2000
Pages
235 - 238
Database
ISI
SICI code
0162-0134(20000701)80:3-4<235:FSAXSO>2.0.ZU;2-S
Abstract
The solvent-free condensation of heptafluorobutanal and pyrrole leads to th e corresponding meso-alkyl-substituted corrole, which was metallated by gal lium chloride to provide the first first-row non-transition-metal corrole. Both the ligand and the complex were characterized by X-ray crystallography . (C) 2000 Elsevier Science S.A. All rights reserved.