We investigate the elementary excitations of quasi-one-dimensional S = 1/2
systems built up from zigzag chains with general isotropic exchange constan
ts, using exact (Lanczos) diagonalization for 24 spins and series expansion
s starting from the decoupled dimer limit. For the ideal one-dimensional zi
gzag chain we discuss the systematic variation of the basic (magnon) triple
t excitation with general exchange parameters and in particular the presenc
e of practically flat dispersions in certain regions of phase space. We ext
end the dimer expansion in order to include the effects of three-dimensiona
l interactions on the spectra of weakly interacting zigzag chains. In an ap
plication to KCuCl3 we show that this approach allows us to determine the e
xchange interactions between individual pairs of spins from the spectra as
determined in recent neutron scattering experiments.