Extraction of lanthanide ions from aqueous solution by modified supercritical CO2: tri-n-butylphosphate plus CO2 and bis-2-ethylhexyl phosphoric acidplus CO2

High-pressure single-phase limit of binary tri-n-butylphosphate (TBP) + CO2 and bis-2-ethylhexyl phosphoric acid (B2EHPA) + CO2 was measured. By a var iable-volume view-cell apparatus, the phase transition pressures of each sy stem were measured at various phase-equilibrium conditions (313.15-333.15 K , 10-25 MPa. 3.7-18.9 mol% TBP and 1.0-45.0 mol% B2EHPA). Based on this dat a, supercritical fluid extraction (SFE) was carried out for lanthanide ions from acidic aqueous solution. In the first place, SFE was carried out for Nd3+ over a wide range of conditions (0-5 M HNO3, 313.15-333.15 K and 10-25 MPa) and optimum SFE process conditions are evaluated. In the second place , SFE was carried out at 313.15 K and 25 MPa for six types of lanthanide io ns (La3+, Ce3+, Nd3+, Sm3+, Eu3+, and Yb3+) from 1 M HNO3 acidic solution a nd the characteristics of different metals on the SFE were compared. (C) 20 00 Elsevier Science B.V. All rights reserved.