An optical method is described to perform instantaneous thermometry along a
line in low-density air seeded with it. Laser-induced fluorescence is gene
rated by exciting the I-2 Cordes bands (D (1)Sigma(u)(+) <--X (1)Sigma(g)()) with a tunable ArF excimer laser near 193 nm. Temperatures from 295 to 6
48 K are measured by fitting the I-2 emission spectrum from 188 to 195 nm t
o a vibrational Boltzmann distribution. Uncertainties for average measureme
nts are typically +/-5% (+/-1 sigma).