Optical reflection spectra of silicon clathrate compounds Ba8AgxSi46-x

Citation
Y. Nozue et al., Optical reflection spectra of silicon clathrate compounds Ba8AgxSi46-x, MOLEC CRYST, 341, 2000, pp. 1313-1318
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Volume
341
Year of publication
2000
Pages
1313 - 1318
Database
ISI
SICI code
Abstract
Optical reflection spectra are measured for Ba8AgxSi46-x (0 less than or eq ual to x less than or equal to 6) at room temperature. A systematic decreas e in the plasmon energy is found with increasing x, indicating that the car rier concentration decreases with increasing x. When x increases, the super conducting transition temperature T-c decreases. An origin of the decrease in T-c is assigned to the decrease in the density or states at the Fermi le vel due to the decrease in the carrier concentration.