Electronically and sterically induced structural distortions in square-planar d(8) complexes

Citation
A. Magistrato et al., Electronically and sterically induced structural distortions in square-planar d(8) complexes, ORGANOMETAL, 19(18), 2000, pp. 3591-3596
Citations number
45
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
18
Year of publication
2000
Pages
3591 - 3596
Database
ISI
SICI code
0276-7333(20000904)19:18<3591:EASISD>2.0.ZU;2-G
Abstract
The solid-state structure of the cationic MeO-Biphep Rh(I) compound [Rh((S) -MeO-Biphep)-(P{OMe}(3))(2))]BF4 (3) has been determined by X-ray diffracti on. The four P-donors deviate markedly from square-planar geometry, with th e phosphite ligands P2 and P2' ca. +/-0.61(7) Angstrom from the P1-Rh-P1' p lane. This distortion resembles that found for PdBr(p-NCC6H4)-((S)-MeO-Biph ep) (1). Density functional calculations on a series of systematically vari ed models of 1 reveal three major components to be responsible for the obse rved distortion from square-planar geometry: (i) attractive aromatic ring p i-pi interactions, (ii) electronic stabilization of coplanar aromatic rings in pseudo-trans positions, and (iii) P-phenyl and MeO-Biphep-phenyl intral igand repulsive steric interactions. Additional DFT studies on the p-tolyl- Binap analogue of i, PdBr(p-NCC6H4)((R)-p-Tol-Binap) (2), explain the sourc e of the extremely long Pd-PB bond distance, 2.437(1) Angstrom, in 2. Despi te the structural similarity between 1 and 2, the calculations rationalize the observation of a pronounced distortion from a square-planar geometry in the former that is essentially absent in the latter.