A. Magistrato et al., Electronically and sterically induced structural distortions in square-planar d(8) complexes, ORGANOMETAL, 19(18), 2000, pp. 3591-3596
The solid-state structure of the cationic MeO-Biphep Rh(I) compound [Rh((S)
-MeO-Biphep)-(P{OMe}(3))(2))]BF4 (3) has been determined by X-ray diffracti
on. The four P-donors deviate markedly from square-planar geometry, with th
e phosphite ligands P2 and P2' ca. +/-0.61(7) Angstrom from the P1-Rh-P1' p
lane. This distortion resembles that found for PdBr(p-NCC6H4)-((S)-MeO-Biph
ep) (1). Density functional calculations on a series of systematically vari
ed models of 1 reveal three major components to be responsible for the obse
rved distortion from square-planar geometry: (i) attractive aromatic ring p
i-pi interactions, (ii) electronic stabilization of coplanar aromatic rings
in pseudo-trans positions, and (iii) P-phenyl and MeO-Biphep-phenyl intral
igand repulsive steric interactions. Additional DFT studies on the p-tolyl-
Binap analogue of i, PdBr(p-NCC6H4)((R)-p-Tol-Binap) (2), explain the sourc
e of the extremely long Pd-PB bond distance, 2.437(1) Angstrom, in 2. Despi
te the structural similarity between 1 and 2, the calculations rationalize
the observation of a pronounced distortion from a square-planar geometry in
the former that is essentially absent in the latter.