Structural characterization of dimercury(1(+)) pentacyanonitrosylferrate(2(-)), Hg-2[Fe(CN)(5)NO]

Authors
Venegas, V Rueda-Morales, G Reguera, E Caleyo, F
Citation
V. Venegas et al., Structural characterization of dimercury(1(+)) pentacyanonitrosylferrate(2(-)), Hg-2[Fe(CN)(5)NO], POWDER DIFF, 15(3), 2000, pp. 193-197
Citations number
16
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
POWDER DIFFRACTION
ISSN journal
08857156 → ACNP
Volume
15
Issue
3
Year of publication
2000
Pages
193 - 197
Database
ISI
SICI code
0885-7156(200009)15:3<193:SCODP>2.0.ZU;2-7
Abstract
The titled compound, Hg-2[Fe(CN)(5)NO], was synthesized and studied by X-ra y powder diffraction, infrared spectroscopy, Mossbauer spectroscopy, and at omic force microscopy. The results arising from this study indicate that th is compound is anhydrous and crystallizes in the P222 orthorhombic symmetry . The unit cell parameters were quantified as a = 16.5905(9) Angstrom, b = 12.3145(8) Angstrom, and c = 8.7576(5) Angstrom. The measured and calculate d density values are D-m = 1.149 g/cm(3) and D-c = 1.145 g/cm(3), respectiv ely, with Z = 2. (C) 2000 International Centre for Diffraction Data. [S0885 -7156(99)00603-X].