ASYMMETRIC HYDROFORMYLATION OF ALLYLIC ALCOHOLS CATALYZED BY RH(I)-(R,S)-BINAPHOS

Authors
NOZAKI K LI WG HORIUCHI T TAKAYA H
Citation
K. Nozaki et al., ASYMMETRIC HYDROFORMYLATION OF ALLYLIC ALCOHOLS CATALYZED BY RH(I)-(R,S)-BINAPHOS, Tetrahedron letters, 38(26), 1997, pp. 4611-4614
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
26
Year of publication
1997
Pages
4611 - 4614
Database
ISI
SICI code
0040-4039(1997)38:26<4611:AHOAAC>2.0.ZU;2-A
Abstract
Chiral lactones 4a-e were synthesized by the asymmetric hydroformylati on of allylic alcohols 1a-e and 5 catalyzed by a rhodium(1) complex of a chiral phosphine-phosphite, (R,S)-BINAPHOS, followed by the silver( I) oxidation. (C) 1997 Elsevier Science Ltd.