REDUCTIVE REARRANGEMENT OF 4C-SUBSTITUTED HEX-2-ENOPYRANOSIDES - SYNTHESIS OF 3-DEOXY GLYCALS

Authors
ACHMATOWICZ O SZECHNER B
Citation
O. Achmatowicz et B. Szechner, REDUCTIVE REARRANGEMENT OF 4C-SUBSTITUTED HEX-2-ENOPYRANOSIDES - SYNTHESIS OF 3-DEOXY GLYCALS, Tetrahedron letters, 38(26), 1997, pp. 4701-4704
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
26
Year of publication
1997
Pages
4701 - 4704
Database
ISI
SICI code
0040-4039(1997)38:26<4701:RRO4H->2.0.ZU;2-F
Abstract
4-C-Substituted alpha-erythro and beta-threo hex-2-enopyranosides i.e. with the 4-OH and 1-OMe groups cis, in contrast to their hens stereoi somers, are cleanly reduced by Lithium aluminum hydride to the respect ive 3-deoxy glycals. (C) 1997 Published by Elsevier Science Ltd.