The spectral and amplitude-time characteristics of HF lasers pumped by a no
nchain chemical reaction and initiated by radially convergent and planar el
ectron beams were investigated. The principal channels leading to the forma
tion of vibrationally excited HF molecules were analysed. It was confirmed
that high efficiencies (similar to 10%) of a nonchain HF laser may be attai
ned only as a result of the simultaneous formation of atomic and molecular
fluorine when the active mixture is acted upon by an electron beam and of t
he participation of molecular fluorine in population inversion. It was show
n that a laser pulse has a complex spectral-temporal profile caused by the
successive generation of P-lines and the overlap during the radiation pulse
of both the rotational lines of the same vibrational band and of individua
l vibrational bands.