Atomic force microscopy was applied to the study of thin Au films depo
sited under ultra-high vacuum conditions on a glass support maintained
at 78 K. A variety of thin gold film structures were thus determined
and characterized ranging from (i) nanometric isolated gold islands, (
ii) nanometric gold structures, to (iii) continuous gold films, all de
pending on the amount of Au deposited. The influence of the amalgamati
on process on the thin Au films topography was studied. The fundamenta
l importance of surface defects on the rate of amalgamation was clearl
y seen. The movement of small Au islands on glass obtained as the resu
lt of thermal decomposition of Au/Hg alloys was observed.