The influence of the surface morphology on the local interactions of a one
monolayer confined Ni film with a root 3-Ag/Si(111) interface with three-di
mensional submicron-sized Ag islands has been studied by synchrotron radiat
ion photoelectron spectromicroscopy with a lateral resolution of 120 nm, Th
e spatially resolved two-dimensional maps and the photoelectron spectra mea
sured after Ni post-deposition at 300 K and following step annealing to 970
K give evidence for the different chemical transformation of the coexistin
g phases, The formation temperature and the stability of the mixed phases h
ave been deduced and discussed. Copyright (C) 2000 John Wiley & Sons, Ltd.