In this paper we propose a mathematical model for calculating XPS intensity
distribution from a textured sample surface covered with a thin film. The
surface roughness is approximated using triangular prisms, Analytical expre
ssions for XPS intensity calculation are given. The results show that the X
PS signals vary significantly in the cases of thin overlayers and high valu
es of the prism slope angle. This model is useful when evaluating the surfa
ce roughness together with the film thickness, Copyright (C) 2000 John Wile
y & Sons, Ltd.