Observation of carbonyl fluoride, ketene, acetic acid and fluorocarbene produced by an electric discharge within a nozzle by molecular beam fourier transform microwave spectroscopy. A reaction via a cycloaddition for carbonyl fluoride and keten?

Authors
Sutter, DH Dreizler, H
Citation
Dh. Sutter et H. Dreizler, Observation of carbonyl fluoride, ketene, acetic acid and fluorocarbene produced by an electric discharge within a nozzle by molecular beam fourier transform microwave spectroscopy. A reaction via a cycloaddition for carbonyl fluoride and keten?, Z NATURFO A, 55(8), 2000, pp. 695-705
Citations number
26
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
ISSN journal
09320784 → ACNP
Volume
55
Issue
8
Year of publication
2000
Pages
695 - 705
Database
ISI
SICI code
0932-0784(200008)55:8<695:OOCFKA>2.0.ZU;2-W
Abstract
A molecular beam Fourier transform microwave spectrometer, designed for the study of chemical reactions within electrical discharges, is described in detail. Applications include the production of carbonyl fluoride, ketene, a cetic acid, and difluorocarbene. For the production of carbonyl fluoride an d ketene with I,1-difluoroethylene and carbon dioxide as precursor molecule s a reaction path via a 2+2 cycloaddition is proposed.