Bis(acetato-O)tetrakis(imidazole-N-3)nickel(II)

Authors
Naumov, P Ristova, M Drew, MGB Ng, SW
Citation
P. Naumov et al., Bis(acetato-O)tetrakis(imidazole-N-3)nickel(II), ACT CRYST C, 56, 2000, pp. E372-E373
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
9
Pages
E372 - E373
Database
ISI
SICI code
0108-2701(200009)56:<E372:B>2.0.ZU;2-W
Abstract
In the title compound, [Ni(C2H3O)(2)(C3H4N2)(4)], the Ni atom is coordinate d centrosymmetrically by four N and two O atoms in an octahedral coordinati on [Ni-N = 1.986 (3) and 2.054 (3) Angstrom; Ni-O = 2.697 (3) Angstrom]. Th e O atoms of the acetate anions form hydrogen bonds to adjacent imidazole m oieties, with the free O atom forming a somewhat shorter bond [N ... O = 2. 679 (3) and 2.870 (4) Angstrom]. The hydrogen bonds give rise to a two-dime nsional layer structure.