The study of magnetic multilayers consisting of electrodeposited Co layers
is gaining significant importance for the application in the field of magne
tic recording. However, there are been few studies on the properties of ele
ctrodeposited Co thin films. in this paper, the relation between morphology
, crystallographic structure and magnetic properties of electrodeposited Co
films on Si(100) and on a polycrystalline Cu substrate has been investigat
ed. Co films of 100-nm thickness on Si and on Cu exhibit similar magnetic p
roperties. It appears that the grain size and the interfacial roughness of
the Co films do not influence significantly the magnetic properties, while
the crystallographic structure plays a predominant role. We have shown that
the pH of the electrolyte influences the fraction of the hcp and fee phase
in the Co film and therefore tunes its magnetic properties. (C) 2000 Elsev
ier Science B.V. All rights reserved.