V. Halpern, THE SIGNIFICANCE OF TEMPERATURE-DEPENDENT DISTRIBUTIONS OF ACTIVATION-ENERGIES, Journal of physics. Condensed matter, 9(25), 1997, pp. 5479-5484
While the response to an electric field of many disordered systems can
be accounted for by postulating that the system contains independent
particles with transition rates having a distribution of energy barrie
rs or activation energies, in order to account for the temperature dep
endence of the experimental results it is often assumed that this dist
ribution depends on temperature. In this paper, the question is examin
ed of the minimum temperature dependence of the energies of the rates
for the individual particles that is required to produce such temperat
ure-dependent distributions for the system. This permits the clarifica
tion of the meaning of a temperature-dependent distribution of activat
ion energies, and also shows that standard techniques such as the meas
urement of thermally stimulated depolarization currents often cannot d
etermine whether or not such a distribution exists.