Rz. Ma et al., The development of carbon nanotubes/RuO2 center dot xH(2)O electrodes for electrochemical capacitors, B CHEM S J, 73(8), 2000, pp. 1813-1816
Carbon nanotubes were refluxed with nitric acid to create acid sites on the
surface. After such treatment, amorphous or nano-scale crystalline RuO2. x
H(2)O can be adhered to the surfaces of carbon nanotubes by a simple method
. RuO2. xH(2)O became more amorphous with decreasing the fraction of carbon
nanotubes. The capacitance can be enhanced significantly by the adherence.
When the weight fraction of RuO2. xH(2)O in the composite electrodes reach
ed 75%, a specific capac- itance of 560 Fg(-1) was achieved. On the other h
and, carbon nanotubes/RuO2. xH(2)O capacitors exhibit excellent power deliv
ery behavior. So the processing of carbon nanotubes/RuO2. xH(2)O composite
electrodes is a new attempt to fabricate supercapacitors with both high ene
rgy and high power density.