The stimulated emission at 722.9 nm is observed by a direct photodissociati
on of the PbI2 molecules with a 266 nm pulse laser. The possible dissociati
on channels are discussed. Two-photon resonant photodissociation mechanism
is used to explain the generation of the 722.9 nm emission. The emission is
measured at different incident laser energy and heat-pipe temperature. The
obtained experimental result is well supported by the photodissociation me
chanism given by us.