Influence of NH4Cl, NH4NO3, and NaNO3 on the simultaneous solubility of ammonia and carbon dioxide in water

Citation
Aps. Kamps et al., Influence of NH4Cl, NH4NO3, and NaNO3 on the simultaneous solubility of ammonia and carbon dioxide in water, J CHEM EN D, 45(5), 2000, pp. 796-809
Citations number
40
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
45
Issue
5
Year of publication
2000
Pages
796 - 809
Database
ISI
SICI code
0021-9568(200009/10)45:5<796:IONNAN>2.0.ZU;2-1
Abstract
New experimental results for the simultaneous solubility of ammonia and car bon dioxide in (about 4 m) aqueous solutions of NH4Cl, NH4NO3, and NaNO3 at (313, 353, and 393) K and total pressures up to about 0.7 MPa are reported . The maximum loading of carbon dioxide to ammonia, i.e., the molar ratio o f carbon dioxide to ammonia, in the liquid phase was about 1 (at 313 K), ab out 0.7 (at 353 K), and about 0.3 (at 393 K). The experimental results are used to assess predictions from a thermodynamic model for the solubility of ammonia and sour gases in aqueous solutions of strong electrolytes.