Gj. Chen et al., The effect of microstructure and secondary phase on magnetic and electrical properties of La-deficient La1-xMnO3-delta (0 <= x <= 0.3) films, J MAGN MAGN, 219(3), 2000, pp. 317-324
The effects of La-deficiency on the microstructure, magnetic and electrical
properties of lanthanum manganite films are reported. By high-resolution t
ransmission electron microscopy observations, the irradiation damages were
found due to the introduction of vacancies. With proper control of La ions,
the magnetic transition temperature was elevated to higher than room tempe
rature. An insulator-metal transition (I-M transition) was observed for all
La1-xMnO3-delta films. The large negative magnetoresistance effect is demo
nstrated. In addition, the influence of the secondary-phase Mn3O4 on the pr
operties of the films is studied. (C) 2000 Elsevier Science B.V. All rights
reserved.