O. Enger et al., Photocurrent generation at a fullerene self-assembled monolayer-modified gold electrode cast with a polyurethane membrane, J MAT CHEM, 10(10), 2000, pp. 2231-2233
Two photoelectrochemical cells based on C-60-SAM-modified gold electrodes h
ave been fabricated and their photoelectric responses with Ar- or O-2-satur
ated electrolyte investigated. High quantum yields under visible light illu
mination and without an external electron sacrificer were observed. A new a
pproach consisting of casting an ion-selective polyurethane membrane on the
C-60-SAM leads to improved stability of the photocurrent generation.