G. Ono et al., One-dimensional double chain composed of carbamoylmethylthio-substituted TTF-based donor in ion radical salt, J MAT CHEM, 10(10), 2000, pp. 2277-2282
Carbamoylmethylthio-substituted TTF-based donors afforded inclusion-type sa
lts with a BF4 counter ion or an F-4-TCNQ acceptor. The crystal structures
of these salts are characterized by a one-dimensional double chain composed
of singly-oxidized donors via SOMO-SOMO interaction and side-by-side S ...
S contacts. Counter ions of BF4 are hydrogen-bonded to the amide groups. O
n the other hand, F-4-TCNQ acceptors are stacked in a channel created by a
stair-like arrangement of donor chains. The thermally activating magnetic s
usceptibility of the F-4-TCNQ complex was interpreted in terms of a double-
chain frustrated spin system.