N. Kawahashi et H. Shiho, Copper and copper compounds as coatings on polystyrene particles and as hollow spheres, J MAT CHEM, 10(10), 2000, pp. 2294-2297
Submicron-sized anionic polystyrene latices have been coated with uniform l
ayers of copper compounds by aging dispersions of the polymer colloid in th
e presence of aqueous solutions of Cu(NO3)(2), urea, and poly(N-vinylpyrrol
idone) at 85 degrees C. The thickness and morphology of the deposited layer
s can be altered by suitable adjustment of the reactant concentrations and
the aging time. Hollow colloidal spheres of metallic copper and copper oxid
e were obtained by calcination of the coated polystyrene latices at elevate
d temperatures in nitrogen and air, respectively.