Synthesis of a family of aluminium benzylphosphonates

Authors
Zakowsky, N Hix, GB Morris, RE
Citation
N. Zakowsky et al., Synthesis of a family of aluminium benzylphosphonates, J MAT CHEM, 10(10), 2000, pp. 2375-2380
Citations number
35
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
JOURNAL OF MATERIALS CHEMISTRY
ISSN journal
09599428 → ACNP
Volume
10
Issue
10
Year of publication
2000
Pages
2375 - 2380
Database
ISI
SICI code
0959-9428(2000)10:10<2375:SOAFOA>2.0.ZU;2-5
Abstract
A family of four aluminium benzylphosphonate phases has been synthesised us ing hydrothermal methods. The effect of changing the synthetic conditions ( starting pH, starting Al : P ratio, aluminium source etc.) has been studied and full structural characterisation of two of the phases by NMR, TGA and X-ray diffraction methods has been completed; Al(OH)(O3PCH2C6H5). H2O, mono clinic P2(1)/c, a = 14.985(9), b = 7.066(5), c = 9.613(9) Angstrom, beta = 113.9(3)degrees, and Al3H(PO3CH2C6H5)(5). H2O, monoclinic P2(1)/c, a = 17.2 497(13), b = 25.7851(18), c = 9.4339(7) Angstrom, beta = 103.567(1)degrees.