Adsorption of carbon monoxide on activated carbon-tin ligand

Citation
Ab. Mohamad et al., Adsorption of carbon monoxide on activated carbon-tin ligand, J MOL STRUC, 550, 2000, pp. 511-519
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
550
Year of publication
2000
Pages
511 - 519
Database
ISI
SICI code
0022-2860(20000905)550:<511:AOCMOA>2.0.ZU;2-W
Abstract
Activated carbon was impregnated with 34.57% SnCl2. 2H(2)O salt and then dr ied at 180 degrees C to produce AC-SnO2 to improve its adsorptive interacti on with CO. Besides the fact that activated carbon has its original differe nt pore sizes for normal gas phase CO adsorption (as in the case of pure ca rbon), the impregnated carbon has additional CO adsorption ability due to t he presence of O-(ads) on the active sites. AC-SnO2 proved to be a superior adsorber of CO than pure carbon when used for H-2 purification in a PSA sy stem. Discernibly, the high adsorptive selectivity of AC-SnO2 towards gas p hase CO portrays a good future for the applicability of this noble adsorben t, since CO has become: a notorious threat to the global ecosystem due to t he current level of air pollution. (C) 2000 Elsevier Science B.V. All right s reserved.