Ab initio prediction of Mn2+OH2/Mn3+OH2 electron transfer reactivity at electron correlation level

An ab initio calculation of electron transfer reactivity of Mn2+OH2/Mn3+OH2 redox system, in gas and in solution, has been made in this paper. The det ailed geometry optimization and the scanning of the potential energy surfac es have been carried out at UMP2 (full)/6-311 + G* level. The relevant ener gy quantities (such as the activation energy and the binding energy) are ca lculated at different levels of theory (HF, MP2, MP3, MP4 and QCISD and cor responding spin-projection PUHF, PMP2 and PMP3) with the same basis set (6- 311 + G*). Both all-electrons and valence electrons have been correlated in energy calculations. The electronic transmission coefficient is calculated using the ab initio potential energy surface slopes and the coupling matri x element determined from the two-state model and the Slater-type d-electro n wave functions. The pair distribution function is obtained using both a c lassical sphere approximation scheme and a novel scheme. The relevant kinet ic parameters are obtained at different ab initio levels in terms of the ne w model. The contact-distance dependence of these parameters and the applic ability of the presented models are also discussed. (C) 2000 Elsevier Scien ce B.V. All rights reserved.