Ns. Fender et al., Preparation of [60]fullerene tris-malonate adducts by addend removal from higher adducts via the electrochemical retro-Bingel reaction, J CHEM S P2, (9), 2000, pp. 1924-1928
Citations number
28
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Systematic application of the electrochemical retro-Bingel reaction to tetr
akis-, pentakis- and hexakis-malonate adducts of C-60, produced tris-adduct
s in ca. 30% yield. Of the tris-adducts obtained, the (trans-4, trans-2, e)
and the (trans-3, trans-4, e) isomers were the major products, while unexp
ectedly, the (e, e, e) and (trans-3, trans-3, trans-3) isomers were formed
in relatively small amounts. New tetrakis-adducts were also formed via the
isomerization reaction as indicated by HPLC studies.