Photochemical transformations of matrix-isolated cycloalkyl nitrites

Authors
Puchowicz, D Adamus, J Gebicki, J
Citation
D. Puchowicz et al., Photochemical transformations of matrix-isolated cycloalkyl nitrites, J CHEM S P2, (9), 2000, pp. 1942-1945
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
ISSN journal
14701820 → ACNP
Issue
9
Year of publication
2000
Pages
1942 - 1945
Database
ISI
SICI code
1470-1820(2000):9<1942:PTOMCN>2.0.ZU;2-#
Abstract
Photochemical transformations of cycloalkyl nitrites isolated in argon matr ices have been studied. In the case of cyclohexyl, cycloheptyl and cyclooct yl nitrites complexes of HNO with the corresponding cycloalkyl ketones were formed. Photochemical irradiation of cyclobutyl nitrite resulted in the fo rmation of 4-nitrosobutanal as the major product. Under similar conditions irradiation of cyclopentyl nitrite gave a mixture of 5-nitrosocyclopentanal and the complex of cyclopentanone and HNO.