The size-controlled TiO2 particles are usually employed in semiconductor de
vices, catalysis and photo-catalysis, adsorption and optical technology. In
this work, the kinetics of the aerosol process involving the precursor tet
raisopropyl orthotitanate (TPT) and water as reactants kept in supercritica
l conditions (using CO2 as solvent) and a detailed description of the fluid
dynamic variables coupled with the statistical distribution of the particl
es inside the reactor are investigated. A turbulent diffusive flow is force
d into the reactor to guarantee a complete conversion of the reactants and
the production of small diameter particles. Furthermore, the particle forma
tion can be well represented by means of the general dynamic equation (GDE)
. To allow a coupling between the solution of the fluid dynamic fields and
the representation of the particle evolution within the reactor, the method
of moments was applied to GDE to determine the most important statistical
variables of a particle. (C) 2000 Elsevier Science S.A. All rights reserved
.