Empirical interatomic potential parameters are determined for group semicon
ductors such as CdS, CdSe, ZnS, and ZnSe. The structural properties of zinc
-blende CdS, CdSe, ZnS, and ZnSe are calculated. A good agreement between t
he calculated and experimental values of the lattice constant, the cohesion
energy, and bulk modulus and its derivative are obtained. The versality of
these empirical potential parameters is confirmed by the calculation of el
astic constants for CdS, CdSe, ZnS, and ZnSe. We have used the molecular-dy
namics methods for the calculations of the thermal expansion and heat capac
ity. The results compare well with available results. (C) 2000 Elsevier Sci
ence S.A. All rights reserved.