Nanosized titania particles are synthesized by the gas-phase oxidation of t
itanium tetrachloride in a high temperature tubular aerosol flow reactor th
at consists of two preheaters for oxygen and vaporized titanium tetrachlori
de, a reaction zone, and a cooling zone for particles. The effect of proces
s parameters on the morphology and structure of titania particles is studie
d. As the preheating temperature of oxygen increases, the average particle
size of titania decreases and the size distribution becomes more uniform. T
he addition of AlCl3 can reduce the particle size, and enhance the rutile w
eight fraction. The effect of reaction temperature (T) on the characteristi
cs of nanosized titania particles is also investigated. The results show th
at the particle size increases with increasing temperature, acid a maximum
rutile fraction is attained at 1200 degrees C and AlCl3 and TiCl4 feed rati
o (X-inlet) of 0.09. Pure rutile titania particles is formed when T=1373 K
and X-inlet=0.25. The average grain size of the particles is 29.0 nm, and t
he BET specific surface area is 23.4 m(2) g(-1). (C) 2000 Elsevier Science
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