J. Rusing et al., Three-dimensional investigation of ceramic/metal heterophase interfaces byatom-probe microscopy, MICROS MICR, 6(5), 2000, pp. 445-451
The results of a three-dimensional atom probe (3DAP) analysis, on a subnano
meter scale, of a ceramic/metal heterophase interface, MgO/Cu, are presente
d. Segregation of Ag, from the Cu (Ag) matrix, at MgO/Cu interfaces is inve
stigated and the Gibbsian interfacial excess of silver is determined; the r
ange is 2.33 x 10(18) to 5.81 x 10(18) m(-2). Also, silver segregation at t
he same MgO/Cu interfaces is analyzed employing a new approach that utilize
s a proximity histogram or proxigram.