Non-Sonogashira-type palladium-catalyzed coupling reactions of terminal alkynes assisted by silver(I) oxide or tetrabutylammonium fluoride

Citation
A. Mori et al., Non-Sonogashira-type palladium-catalyzed coupling reactions of terminal alkynes assisted by silver(I) oxide or tetrabutylammonium fluoride, ORG LETT, 2(19), 2000, pp. 2935-2937
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
19
Year of publication
2000
Pages
2935 - 2937
Database
ISI
SICI code
1523-7060(20000921)2:19<2935:NPCROT>2.0.ZU;2-M
Abstract
[GRAPHICS] Palladium-catalyzed reaction of aryl and alkenyl halides with terminal alky nes in the presence of silver(I) oxide as an activator furnishes various ar ylated or alkenylated alkynes in good to excellent yields, The similar coup ling reaction is also found to proceed using tetrabutylammonium fluoride (T BAF) or tetrabutylammonium hydroxide (TBAOH) as an activator.