A. Mori et al., Non-Sonogashira-type palladium-catalyzed coupling reactions of terminal alkynes assisted by silver(I) oxide or tetrabutylammonium fluoride, ORG LETT, 2(19), 2000, pp. 2935-2937
[GRAPHICS]
Palladium-catalyzed reaction of aryl and alkenyl halides with terminal alky
nes in the presence of silver(I) oxide as an activator furnishes various ar
ylated or alkenylated alkynes in good to excellent yields, The similar coup
ling reaction is also found to proceed using tetrabutylammonium fluoride (T
BAF) or tetrabutylammonium hydroxide (TBAOH) as an activator.